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Bar Keepers Friend Granite & Stone Cleaner & Polish, Pump Spray-02/19/2020
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Granite & Stone Cleaner & PolishStructure such as solid, liquid, aerosol etc.
Form: pump sprayDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 13, 20245240 Walt Place
Indianapolis IN 46254
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 007732-18-5 -- -- -- -- -- 000056-81-5 -- -- -- -- -- 000067-63-0 -- F, Xi -- -- -- -- 000057-55-6 -- -- -- -- -- 068439-46-3 -- -- -- -- -- 006440-58-0 -- -- -- -- -- 055406-53-6 -- -- -- -- -- 025265-71-8 -- -- -- -- -- 000098-55-5 -- -- -- -- -- 018479-58-8 -- -- -- -- -- 008008-57-9 -- -- -- -- -- 000075-21-8 -- F+, T -- -- -- -- 000123-91-1 -- F, Xi -- -- -- -- 000050-00-0 -- T -- -- -- -- 000067-56-1 -- F, T -- -- -- -- 000123-35-3 -- -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
Chemical Function Purpose served by this chemical.Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Water
Coupling Agent
007732-18-5
231-791-2-- No -- -- -- No No Glycerin
Coupling Agent
000056-81-5
200-289-5-- No -- -- -- No No Isopropanol
Coupling Agent
000067-63-0
200-661-7-- No H225, H319, H336 P102, P210, P233, P241, P242, P243, P261, P264, P271, P280, P405, P501, P303+P361+P353, P370+P378, P337+P313, P305+P351+P338, P304+P340, P312, P403+P233, P403+P235 No No Propylene glycol
Coupling Agent
000057-55-6
200-338-0-- No -- -- -- No No C9-11 Pareth-3
Surfactant
068439-46-3
500-446-0-- No H319 P280, P305+P351+P338, P310 No No DMDM hydantoin
Preservative
006440-58-0
229-222-8-- No H302 P301+P312 No No 3-Iodo-2-propynylbutylcarbamate
Preservative
055406-53-6
259-627-5-- No -- -- -- No No Dipropylene glycol
Fragrance
025265-71-8
246-770-3-- No -- -- -- No No alpha-Terpineol
Fragrance
000098-55-5
202-680-6-- No H315, H319 P280, P302+P352, P305+P351+P338 No No 2,6-Dimethyl-7-Octen-2-Ol
Fragrance
018479-58-8
242-362-4-- No H315, H319 P264, P280, P302+P352, P305+P351+P338, P332+P313, P337+P313, P362 No No Citrus Aurantium Dulcis Oil (Orange oil)
Fragrance
008008-57-9
---- No -- -- -- No No Ethylene oxide
--
000075-21-8
200-849-9-- Yes H220, H230, H280, H301, H314, H318, H331, H335, H336, H340, H350, H360, H360Fd, H372 -- No No 1,4-Dioxane
--
000123-91-1
204-661-8-- Yes H225, H319, H335, H351 P210, P233, P240, P241, P242, P243, P280, P303+P361+P353, P370+P378, P403+P235, P501 Yes No Formaldehyde
--
000050-00-0
200-001-8-- Yes H301, H311, H314, H317, H331, H341, H350 -- No No Methanol
--
000067-56-1
200-659-6-- Yes H225, H331, H311, H301, H370 -- No No Myrcene
--
000123-35-3
204-622-5-- Yes H226, H304, H315, H319, H400, H410 P273, P280, P301+P310, P331, P302+P352, P305+P351+P338, P501 No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H220 : Extremely flammable gasH225 : Highly flammable liquid and vapourH226 : Flammable liquid and vapourH280 : Contains gas under pressure; may explode if heatedH301 : Toxic if swallowedH302 : Harmful if swallowedH304 : May be fatal if swallowed and enters airwaysH311 : Toxic in contact with skinH314 : Causes severe skin burns and eye damageH315 : Causes skin irritationH317 : May cause an allergic skin reactionH318 : Causes serious eye damageH319 : Causes serious eye irritationH331 : Toxic if inhaledH335 : May cause respiratory irritationH336 : May cause drowsiness or dizziness.H340 : May cause genetic defectsH341 : Suspected of causing genetic defects.H350 : May cause cancer.H351 : Suspected of causing cancerH360 : May damage fertility or the unborn childH370 : Causes damage to organsH372 : Causes damage to organsH400 : Very toxic to aquatic lifeH410 : Very toxic to aquatic life with long lasting effects
- P102 : Keep out of reach of childrenP210 : Keep away from heat/sparks/open flames/hot surfacesP233 : Keep container tightly closedP240 : Ground/bond container and receiving equipmentP241 : Use explosion-proof electrical/ventilating/light/…/equipmentP242 : Use only non-sparking toolsP243 : Take precautionary measures against static dischargeP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP264 : Wash … thoroughly after handlingP271 : Use only outdoors or in a well-ventilated areaP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP310 : Immediately call a POISON CENTER or doctor/physicianP312 : Call a POISON CENTER or doctor/physician if you feel unwellP331 : Do NOT induce vomitingP362 : Take off contaminated clothing and wash before reuseP301+P310 : IF SWALLOWED: Immediately call a POISON CENTER or doctor/physicianP301+P312 : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP302+P352 : IF ON SKIN: Wash with soap and waterP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP304+P340 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP332+P313 : If skin irritation occurs: Get medical advice/attentionP337+P313 : Get medical advice/attentionP370+P378 : In case of fire: Use … for extinctionP405 : Store locked upP501 : Dispose of contents/container to
- GHS02 : FlammableGHS04 : Compressed GasGHS05 : CorrosiveGHS06 : ToxicGHS07 : IrritantGHS08 : Health HazardGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :February 19, 2020 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING1 0 0 Measure of Alkalinity/Acidity of substance or preparation where a level of 7 is considered as neutral.
pH Levels6.6 -
SVHC declaration
Warning: This product contains Substances of Very High Concern (SVHC).
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Warnings
Hazard Statements
This product is a consumer product and is labeled in accordance with the US Consumer Product Safety Commis- sion regulations which take precedence over OSHA Hazard Communication labeling.
Precautionary Statements
General
None.
Prevention
None.
Response
None.
Storage
None.
Disposal
None. -
Acute health effects
From SDS:
Hazards Identification
Emergency Overview
None.
Potential Health Effects
Eye Contact: May cause mild irritation.
Skin Contact: May cause mild irritation.
Inhalation: None expected under normal use conditions.
Ingestion: Swallowing may cause gastrointestinal irritation with nausea, vomiting and diarrhea. -
Chronic health effects
From SDS:
No information. -
Carcinogenicity
None of the components at 0.1 percent or greater are classified as a carcinogen by IARC, NTP, ACGIH, or OSHA.
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Handling information
Avoid eye contact. Wash hands after use. Store in a cool, well-ventilated area. Keep in original containers. Protect containers from physical damage. -
Disposal information
Dispose of in accordance with all local, regional, national, provincial, territorial and international regulations
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California Prop. 65 Warning
This product contains the following chemicals known to the State of California to cause cancer or reproductive toxicity:
Ethylene oxide 75-21-8 <0.002 ppm Cancer, female reproductive, toxicity, male reproductive, toxicity, developmental
1,4-dioxane 123-91-1 <0.02 ppm cancer
Formaldehyde 50-00-0 <1 ppm cancer
Methanol 67-56-1 <10 ppm developmental
Myrcene 123-35-3 <0.21 ppm Cancer, female reproductive, toxicity, male reproductive, toxicity, developmental -
First Aid
Eye Contact: Flush eyes with water for several minutes while lifting the upper and lower lids. Remove contact lenses if present and easy to do, then continue flushing. Get medical attention if irritation persists.Skin Contact: Wash with soap and water. Get medical attention if irritation persists.Inhalation: None required under normal use conditions. If mists are generated and irritation is experienced, move to fresh air. Get medical attention if symptoms persist.Ingestion: Rinse mouth with water. Do not induce vomiting. Get medical attention.
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